Divalent Metal Complexes Of Azosulfamethaxazole: Synthesis And Characterization With Study Some Of Their Applications

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Duaa Jameel Jasim , Alyaakhider Abbas

Abstract

By diazotization and coupling for theobromine and sulfamethoxazole, the novel [4-(8-theobromine azo) sulfamethoxazole] (TAS)has been produced. To make new complexes, the ligand (TAS) was reacted with [Pd (II), Pt (II), and Co(II)]. Spectroscopic methods, thermal analysis, molar conductance data, and magnetic measurements were utilized to analyze both the (TAS) ligand and its metal complexes. The technique of mole ratio was used to determine the stoichiometric of the complexes, which was [1:2] [M:L]except Pd(TAS) it found[1:1]. The complexes of Pt(II) and Pd(II) exhibited square planar geometry, whereas Co(II) was determined to be octahedral geometry. For the TAS ligand and its complexes, the dyeing performance and antibacterial properties were studied. The Palladium complex was also investigated as an antioxidant.

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